Nanocomposites Electrolytes for Intermediate Temperature Polymer Electrolyte Fuel Cells
Among the possible systems investigated for energy production with low environmental impact, fuel cells are very promising as electrochemical power sources both for stationary energy production and application in portable technology and electric vehicles. Polymeric electrolyte membrane fuel cells (PEMFCs) are the most promising candidates for the latter application.
Wetting Layer erosion during formation of InAs/GaAs(001) Quantum Dots
One of the puzzling aspects of the self-assembled QDs is that the nucleated 3D volume is far larger than that being deposited in the narrow coverage range where the entire nucleation process is completed. Resercher from NAST Centre have studied a peculiar feature, recently discovered [1], at the origin of this phenomenon, which is associated with mature 3D QDs,…
Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectrometry (EDS)
LEO 35 Field Emission by Zeiss©
Characteristics
• GEMINI® based Field emission e-beam column capable of ultra high resolution SEM up to 25 KV.
• Achieves a similar low energy spread compared to a cold field emission source, but with a much higher emission current and much higher beam stability.
• Featuring a TV camera and three detectors, i.e. (i) secondary electrons detector, (ii) back-scatter electrons detector (EBSD) , (iii) In-lens detector for ultra high resolution imaging (<10nm).
• Equipped with an energy dispersive x-Ray spectrometer (EDS) from Oxford INCA© allowing for acquisition of sample emitted x-rays. Accompanying software with embedded database of reference spectra for elements identification/recognition, compositional nano-analysis and x-ray mapping.
• Automated stage controlled by a joystick with x-y-z translations, z rotation (full 360° range) and x tilting (up to 90° tilt) for ultra high precision sample positioning.
• Vacuum system (a rotary pump plus a turbo pump) to achieve chamber vacuum of less than 2 x 10-6 mbar.
• Dynamic vibration-damper.
• Several stubs settings and adaptors for mounting samples on the stage.
• Sample preparation desk.
• Sputter-coater to metallize non-conductive samples (with gold or other target).
Some Results
SEM is a common tool to address a variety of aspects in material research and nanotechnology. For illustrative purposes, some examples of SEM work in a variety of research areas (e.g energy, environment, biotechnology and nanotechnology in general) are reported here. As far as energy and environment are concerned, ceramics and nanostructured materials are key in applications such as fuel cells and chemical sensors. Fig.1 shows a surface micrograph of a composite porous electrode (cathode) designed for Solid Oxide Fuel Cell applications and fabricated by Pulsed Laser Deposition technique. Pd-Au metal droplets have been deposited and condensed on a continuous open La0.8Sr0.2Co0.8Fe0.2O3-δ network, previously grown on a dense polycrystalline stabilized ZrO2. Mixed ionic and electronic properties of La0.8Sr0.2Co0.8Fe0.2O3-δ assisted by the electrical properties of metal droplets at high temperature, reduce the cathode polarization in SOFCs.
Figure 1. Surface of a composite porous electrode (cathode) designed for SOFC applications and fabricated by Pulsed Laser Deposition technique. Pd-Au metal droplets were deposited onto a continuous open La0.8Sr0.2Co0.8Fe0.2O3-δ network grown on dense polycrystalline stabilized ZrO2.
Another class of fuel cells are based on the usage of polymeric “Proton Exchange Membranes” (PEM) as the fuel cell electrolyte. Nafion is the best performing polymer currently available for this application but, amongst other drawbacks, suffers of a marked drop in conductivity for working temperatures above 90°C due to morphological transitional and de-hydration. A variety of composite membrane, i.e. hybrid structures of Nafion with dispersed fillers, are under investigation to overcome this problem. Figure 2 shows an example of Nafion mixed with an inorganic phase “sulfonate diphenyl silane diol” (SDPSD), appearing as “bright” islands in the photos. The PEM performances improve based on the content and distribution of the SDPSD. Thermal treatment is one way of controlling the microstructure of the composite structure. SEM micrographs clearly shows that heating the samples at 170 °C induces a finer dispersion of the filler, yielding more minute SDPSD clusters. The limited electronic conductivity of this material makes it difficult to analyze with the SEM.
Figure 2. Two SEM pictures of the Nafion/SDPSD 70:30 composite membrane for PEM fuel cells. Photos selected demonstrate the effect of the thermal treatment at 170°C on the dispersion SDPSD in the microstructure. Sample “as-prepared” (far left) and the “heat-treated” one (left) exhibit different dispersion of SDPSD islands within the Nafion matrix, highlighting a size reduction of the SDPSD clusters induced by the thermal treatment.
SEM imaging is also crucial for the characterization of nanostructured materials for biological applications. Within biotechnology, tissue engineering combines the fields of engineering, chemistry, biology, and medicine to fabricate replacement tissues able to restore, maintain, or improve structurally and functionally damaged organs. Polymeric scaffolds for stem cells growth and differentiation represent an active research topic. Some scaffolds are fabricated by electrospinning as highly interconnected porous polymeric networks. Figure 3 shows a SEM image of nanostructured PLA electrospun nanofibers endowed with nanopores. Such fibres are multiscale features, having lengths in the centimetre range, micrometric and sub-micrometric diameters and nanoscale roughness/porosity. The various length-scales can be largely tuned and tailored through processing parameters.
Figure 3. SEM image of PLA electrospun nanofibers with nanopores. The fibres have a multiscale geometry with lengths in the centimetre range, diameters between few tens of nanometers and few micrometers, and nanoscale porosity. Length-scales can be tuned and tailored through processing parameters. Controlled porosity is important also for drug delivery.
The topics briefly highlighted in the examples are discussed in greater details in several papers. The interested reader can consult the selected papers cited in the reference.
SEM capabilities go beyond pure geometrical and morphological information, highlighted in the previous examples. In fact backscattered electrons and EDS can be used to obtain compositional data. In the next example in Figure 4, a carbon nanoparticle of about 400 nm deposited from the environment onto a substrate made of nanoporous Si. The X-ray spectra shown on the left were collected with the EDS at two different locations pointed out in the SEM micrograph, i.e. at point (1) centered on the nanoparticle and at point (2) away from it. From comparison, the missing peak in the spectrum collected at site (2) is characteristic of C, which reveals the chemical nature of the nanoparticle.
Figure 4: Micro-analisys by EDS of a 400nm carbon particle (site 1) deposited from the environment onto a nanoporous Si substrate. The nature of the nanoparticle is highlighted as a “difference”, because the yellow spectrum at site (2) is missing a peak characteristic of carbon and present in the red spectrum at site (1).
References on SOFC and PEM
[1] D. Z. de Florio, R. Muccillo, V. Esposito, E. Di Bartolomeo and E. Traversa, “Preparation and Electrochemical Characterization of Perovskite/YSZ Ceramic Films”, J. Electrochem. Soc., 152 (1), A88, (2005).
[2] V. Esposito, D. Z. de Florio, F.C. Fonseca, E.N.S. Muccillo, R. Muccillo and E. Traversa, “Electrical properties of YSZ/NiO composites prepared by a liquid mixture technique”, J. Eur. Ceram. Soc., 25, 2637, (2005).
[3] Deganello, V. Esposito, E. Traversa and M. Miyayama. “Cathode performance of nostructured La1-aSraCo1-bFebO3-d on a Ce0.8Sm0.2O2 electrolyte prepared by citrate-nitrate auto-combustion”, F J. Electrochem. Soc., 154 (2), A89, (2007).
[4] Barbara Mecheri, Alessandra D’Epifanio, Enrico Traversa, Silvia Licoccia. “Effect of an ormosil-based filler on the physico-chemical and electrochemical properties of Nafion membranes”, J. Power Sources, 169 (2007) 247–252.
References on Chemical Sensors
[5] M.L. Grilli, E. Di Bartolomeo, A. Lunardi, L. Chevallier, S. Cordiner and E. Traversa, “Planar Non-Nernstian electrochemical sensors: field test in the exhaust of a spark ignition engine”. Sensors and Actuators B, 108 (2005) 319-325
[6] L. Chevallier, M.L. Grilli, E. Di Bartolomeo and E. Traversa. “Non-Nernstian planar sensors based on YSZ with Ta (10 at.%)-doped nanosized titania as sensing electrode for high temperature applications”. International Journal of Applied Ceramic Technology, 3 [5] 393-400 (2006)
References on Tissue Engineering
[7] E. Traversa, B. Mecheri, C. Mandoli, S. Soliman, A. Rinaldi, S. Licoccia, G. Forte, F. Pagliari, S. Pagliari, F. Carotenuto, M. Minieri, P. Di Nardo. “Tuning Hierarchical Architecture of 3D Polymeric Scaffolds for Cardiac Tissue Engineering”, J. Exp. Nanoscience, (accepted sept. 2007).
Prof. Silvia Morante
Contact Details
Office: Physics Department
Tel: +39 06 72594554
Fax: +39 06 2023507
Research Activity
- Folding versus misfolding: physiological and pathological role of metal
- The role of metals in neurodegenerative diseases – Alzheimer, BSE and Parkinson
- Structural studies of biomolecules by XAS (X-ray Absorption Spectroscopy)
- Numerical simulation based approaches (Molecular Dynamics, Monte Carlo, Car-Parrinello)
Recent Publications
[1] V. Minicozzi, S. Morante, G.C. Rossi, F. Stellato, K. Jansen, The role of metals in misfolding and aggregation processes: X-ray spectroscopy and numerical simulations, in From Computational Biophysics to System Biology (CBSB07), Proceedings of the NIC Workshop 2007, 36: 223
[2] S. Furlan, F. Guerrieri, G. La Penna, S. Morante, G.C. Rossi, Studying the Cu binding sites in the PrP N-terminal region. A test case for ab initio simulations, European Biophysics Journal, 36: 841-845 (2007)
[3] S. Furlan, G.La Penna, F. Guerrieri, S. Morante, G.C.Rossi, Ab initio simulations of Cu binding sites on the N-terminal region of PrP, Journal of Biological Inorganic Chemistry, 12(4), 571-583, (2007)
[4] S. Furlan, F. Guerrieri, G.La Penna, S. Morante, G.C. Rossi, Ab initio simulations of Cu binding sites in the N-terminal region of PrP, in From Computational Biophysics to System Biology, J. Meinke, O. Zimmermann, S. Mohanty, U.H.E.Hansmann (Editors) John von Neumann Institute for Computing, Juelich, NIC Series, 34, 153-156, (2006).
[5] S. Morante, G. C. Rossi, M. Testa, The stress tensor of a discrete system: an exercise in Statistical Mechanics, J. Chem. Phys., 125, 034101 (2006).
[6] F. Stellato, G. Menestrina, M. Dalla Serra, C. Potrich, R. Tomazzolli, W. Meyer-Klaucke, S. Morante, Metal binding in amyloids beta peptides shows both intra- and inter-peptide coordination modes, European Biophysics Journal, 35(4), 340 (2006).
[7] S. Morante, C. Poltrich, R. González-Iglesias, C. Meneghini,W. Meyer-Klaucke, G. Menestrina, M. A. Pajares, M. Gasset, Inter- and Intra-octarepeat Cu(II) Site Geometries in the Prion Protein. Implication in Cu(II) binding cooperativity and Cu(II)-mediated assemblies, J. Biol. Chem. 279, 11753 (2004).
[8] G. La Penna, S. Morante, A. Perico, G.C. Rossi, Designing generalized statistical ensembles for numerical simulations of biopolymers, J. Chem. Phys., 121, 10725 (2004).
[9] M. Benfatto, S. Della Longa, Z. Wu, Y. Qin, G. Pan, S. Morante, The role of Zn in the interplay among Langmuir-Blodgett Multi-Layer and Myelin Basic Protein: a quantitative analysis of XANES spectra, Biophysical Chemistry, 110, 191 (2004).
[10] G. La Penna, V. Minicozzi, S. Morante, G.C. Rossi, Tuning force-field parameters by pressure measurements in micro-canonical simulations, International Journal of Modern Physics C., 15, 205 (2004).
Prof. Lorenzo Stella
Contact Details
Office: Department of Science and Chemical Technologies
Tel: +39 06 72594463
Fax: +39 06 72594328
Research Activity
- 3-D structures of peptides in solution
- Peptide-membrane interactions
- Biomolecular electronics
- Molecular recognition and chiral discrimination
- Computational chemistry and molecular modeling
Recent Publications
[1] L. Stella, G. Bocchinfuso, E. Gatto, C. Mazzuca, M. Venanzi, F. Formaggio, C. Toniolo, A. Palleschi and B. Pispisa. “Peptide foldamers: from spectroscopic studies to applications”. Reviews in Fluorescence 2007. C. D. Geddes and J. R. Lakowicz (Eds.), Springer, New York, (2007).
2] E. Gatto, C. Mazzuca, L. Stella, M. Venanzi, C. Toniolo, B. Pispisa. “Effect of peptide lipidation on membrane perturbing activity: a comparative study on two trichogin analogues”. J. Phys Chem. B., 110: 22813 (2006).
3] M. Venanzi, E. Gatto, G. Bocchinfuso, A. Palleschi, L. Stella, C. Baldini, F. Formaggio, C. Toniolo. ”Peptide folding dynamics: a time-resolved study from the nanosecond to the microsecond time regime”. J. Phys. Chem. B, 110: 22834 (2006).
4] B. Pispisa, L. Stella, C. Mazzuca, M. Venanzi. “Trichogin topology and activity in model membranes as determined by fluorescence spectroscopy” . Reviews in fluorescence 2006, C. D. Geddes and J. R. Lakowicz (Eds.), Springer, New York, pp. 47 (2006).
5] E. Gatto, M. Venanzi, A. Palleschi, L. Stella, B. Pispisa, L. Lorenzelli, C. Toniolo, F. Formaggio, G. Marletta. ”Self-assembled peptide monolayers on interdigitated gold microelectrodes” . Mat. Sci. Eng. C., 26: 918 (2006).
6] C. Carta, F. Pantaleoni, G. Bocchinfuso, L. Stella, I. Vasta, A. Sarkozy, C. Digilio, A. Palleschi, A. Pizzuti, P. Grammatico, G. Zampino, B. Dallapiccola, B. D. Gelb, M, Tartaglia. “Germline missense mutations affecting KRAS isoform B are associated with a severe Noonan syndrome phenotype” . Am. J. Hum. Gen., 79: 129 (2006).
Prof. Nicola Rosato
Contact Details
Office: Department of Experimental Medicine and Biochemical Sciences
Tel: +39 06 72596471
Fax: +39 06 72596465
Research Activity
Fields of interest: structure and function of biological macromolecules under high pressure and electromagnetic field. Application of optical spectroscopy and Near Infrared Spectroscopy “in vivo”. Smart nanomaterials in biology and medicine. From 1991 is a member of the commission for the medical application of informatics at the Medical School of the “Tor Vergata” University. From March 2000, is Full Professor in Biochemistry in the Faculty of Medical EngineeringFrom December 2002 is director of the Medical Engineering Service in the “Tor Vergata” University Hospital.N. Rosato is author of about 70 scientific publications (60 on international journals) in the fields of optical spectroscopy of biological molecules, fluorescence instrumentation and medical informatics.
Recent Publications
[1] Bottini M, D’Annibale F, Magrini A, Cerignoli F, Arimura Y, Dawson MI, Bergamaschi E, Rosato N, Bergamaschi A, Mustelin T., “Quantum dot-doped silica nanoparticles as probes for targeting of T-lymphocytes”, Int. J. Nanomedicine, 2(2):227-33, (2007)
[2] Bottini M, Cerignoli F, Tautz L, Rosato N, Bergamaschi A, Mustelin T., “Adsorption of streptavidin onto single-walled carbon nanotubes: application in fluorescent supramolecular nanoassemblies”, J. Nanosci. Nanotechnol. 6(12), 3693-8 (2006)
[3] Nicolai E, Di Venere A, Rosato N, Rossi A, Finazzi Agro’ A, Mei G., “Physico-chemical properties of molten dimer ascorbate oxidase”, FEBS J. , 273(22):5194-204. (2006)
[4] Iucci G, Rossi L, Rosato N, Savini I, Duranti G, Polzonetti G., “The interaction of the polyphenylacetylene surface with biological environments studied by XPS, RAIRS and biological tests”, J Mater Sci Mater Med. 17(9):779-87, (2006)
[5] Bottini M, Cerignoli F, Dawson MI, Magrini A, Rosato N, Mustelin T., “Full-length single-walled carbon nanotubes decorated with streptavidin-conjugated quantum dots as multivalent intracellular fluorescent nanoprobes”, Biomacromolecules, 7(8):2259-63, (2006)
[6] Bottini M, Magrini A, Rosato N, Bergamaschi A, Mustelin T., “Dispersion of pristine single-walled carbon nanotubes in water by a thiolated organosilane: application in supramolecular nnoassemblies”, J Phys Chem B.,20; 110 (28) : 13685-8, (2006)
[7] Bottini M, Magrini A, Di Venere A, Bellucci S, Dawson MI, Rosato N, Bergamaschi A, Mustelin T. “Synthesis and characterization of supramolecular nanostructures of carbon nanotubes and ruthenium-complex Luminophores”, J Nanosci Nanotechnol., 6(5):1381-6, (2006)
[8] Mei G, Di Venere A, Rosato N, Finazzi-Agro A., “The importance of being dimeric”, FEBS J., 272(1):16-27, (2005), Review.
[9] Iucci G, Infante G, Rossi L, Polzonetti G, Rosato N, Avigliano L, Savini I, Catani MV, Palacios AC., “Albumin-containing sol-gel glasses: chemical and biological study”, J Mater Sci Mater Med., 15(5):601-6, (2004)
Education
The NAST mission is to serve the next generation of researchers in nanotechnology at the Bachelor, Master, PhD, and Postdoctoral levels.
PhD Schools
PhD Program in Nanostrucutres and Nanotechnologies
a Joint Program between Università degli Studi di Milano Bicocca and Università degli Studi di Roma Tor Vergata
Ph.D. Program in Materials for Environment and Energy (PDF)
a Joint Ph.D. Program with The University of Tokyo, Research Center for Advanced Science and Technology and The University of Florida, Department of Materials Science and Engineering.
PhD Program in Physics
in collaboration with Physics Department, Università degli Studi di Roma Tor Vergata
Schools
1st Doctorate School in Nano – Materials & Biomaterials (May 2007) Group Photo
Prof. Giuseppe Gorini
Contact Details
Office: Università degli Studi di Milano Bicocca, Piazza della Scienza 3, Milano
Tel: +39 02 6448 2312
Academic career
1986 – 1988 Phd student, Scuola Normale Superiore – Pisa
1989 – 1990 Researcher, IFP-CNR, Milan
1990 – 1998 Researcher, Universita’ degli Studi di Milano
1998 – 2000 Researcher, Universita’ degli Studi di Milano-Bicocca
2000 – present Associate Professor, Universita’ degli Studi di Milano-Bicocca
Research Activity
Neutron spectroscopy in thermonuclear plasmas.
Neutron spectroscopy for materials science
Physics of high temperature plasmas
Application of neutron-based techniques to Cultural Heritage research
Teaching
Electromagnetism and optics, degree in Environmental Science.
Physics of Plasmas, degree in Physics.
Supervisor of undergraduate and Ph D students in Physics.
Recent Publications
[1] G. Gorini et al, The resonant detector and its application to epithermal neutron spectroscopy, Nucl. Instr. and Meth. A, 529, 293 (2004).
[2] C. Andreani, G. Gorini, E. Perelli-Cippo, A. Pietropaolo, N. Rhodes, E. S. Schooneveld, R. Senesi, M. Tardocchi, A resonant detector for high-energy inelastic neutron scattering experiments, Appl. Phys. Lett., 85, 5454 (2004).
[3] J Källne, L Ballabio, J Frenje, S Conroy, G Ericsson, M Tardocchi, E Traneus, G.Gorini, Observation of the Alpha Particle “Knock-On” Neutron Emission from Magnetically Confined DT Fusion Plasmas, Phys Rev Lett., 85, 1246 (2000).
[4] G.Gorini, P.Mantica, G.M.D.Hogeweij, F.De Luca, A.Jacchia, J.A.Konings, N.J.Lopes Cardozo, M.Peters, Simultaneous Propagation of Heat Waves Induced by Sawteeth and ECH Power Modulation in the RTP Tokamak, Phys. Rev. Lett., 47, 2038 (1993).
Prof. Silvia Licoccia
Contact details
Office: Department of Chemical Science and Technology
Tel: +39 06 72594386
Lab: +39 06 72594479
Fax: +39 06 72594328
Research Activity
SL is Professor of Chemistry in the Faculty of Engineering of the University of Rome Tor Vergata.
- President of AICIng (Italian Association Chemistry for Engineering)
- Deputy Director of NAST, Center for Nanoscience, Nanotechnology and Innovative Instrumentation at Tor Vergata
- Director of the Teaching Supervising Committee of the International Ph.D. Program in Materials for Health, Environment and Energy
- Associate Editor of the International Journal of Nanoscience
- Manager responsible for the monitoring and evaluation of Natural Sciences Teaching Activities of the Faculty of Engineering, University of Rome Tor Vergata
- Director of the Italy-Quebec Joint Laboratory on Nanostructured Materials for Energy, Catalysis and Biomedical Applications.
Professional Memberships
Executive Committee of the European Section of The Electrochemical Society (web site)
Materials Research Society (web site)
Royal Society of Chemistry (web site)
American Chemical Society (web site)
Interuniversity Consortium for Materials Science and Technology (web site)
Italian Association Chemistry for Engineering (AICIng) (web site)
Italian Chemical Society (SCI) (web site)
Director of a research group comprising 2 Research Associates, 1 Technician, 4 Post-docs and 11 Graduate Students.
The research activity is mainly focused on the following topics:
- Development of nanostructured materials for Polymeric, Solid Oxide and Microbial Fuel Cells and for gas sensors for environmental monitoring.
- Synthesis and spectroscopic characterization of new materials for energy, environmental and biomedical applications.
- Multinuclear NMR spectroscopy and its application to kinetic and structural studies. Investigation of the electronic and molecular structure of paramagnetic derivatives by means of NMR spectroscopy.
- Nanomechanics.
SL is co-author of over 250 scientific publications (175 on international refereed Journals) and about 250 scientific oral contributions at international conferences, meetings and schools.
Active Research Programs
- CARISMA Coordination Action for Research on Intermediate and high temperature Specialised Membrane electrode Assemblies. (EU; € 15,000; Local PI).
- Italy-Quebec Joint Laboratory on Nanostructured Materials for Energy, Catalysis and Biomedical Applications (MAE , Italian Ministry for Foreign Affairs; € 320,000; Director).
- Cooperation program with the University of Uppsala (Sweden): Novel methods for characterization of the properties of functional interfaces and nanostructured materials. (MiUR, Italian Ministry for University and Research; € 10,000; Local PI).
- Cooperation between the NAST Center and the International Center for Materials Nanoarchitectonics (MANA) at the National Institute for Materials Science, Tsukuba (Japan): Materials for Energy (€ 10,000; Local PI).
- Development of MEC-based devices for the production of bio-hydrogen. (MATTM, Italian Ministry for the Environment; € 456.000, PI).
- PC-SOFCs, Protonic Conductors Solid Oxide Fuel Cells based on nanostructured proton conductors: from materials synthesis to prototype fabrication. (MiUR PRIN, Italian Ministry for University and Research; € 130,000; PI).
- Sustainable hydrogen production and waste treatment via MEC technology. (FILAS; € 138,000; Local PI).
- Valorization of winemaking by-products and waste by application of innovative technologies for extraction of natural products of high added value (AGER; € 100,000, Local PI)
Other Activities
Co-organizer of different conferences and symposia under the frame of the Material Research Society, Electrochemical Society, AICIng, European Ceramic Society.
Teaching:
Chemistry, BEng in Medical and Energetic Engineering (90 hours/average 150 students/year)
Chemistry 1, BEng in Informatic Engineering (60 hours/average 50 students/year)
Environmental monitoring, MSc in Environmental Engineering (50 hours/average 25 students/year)
Recent Publications (selected)
♦ S. Pagliari, A. C. Vilela-Silva, G. Forte, F. Pagliari, C. Mandoli, G. Vozzi, S. Pietronave, M. Prat, S. Licoccia, A. Ahluwalia, E. Traversa, M. Minieri, P. Di Nardo: Cooperation of biological and mechanical signals in cardiac progenitor cell differentiation. Advanced Materials, 2011, 23, 514-518
♦ A. Rinaldi, S. Licoccia, E. Traversa: Nanomechanics for MEMS: A Structural Design Perspective. Nanoscale, 2011, 3, 811-824
♦ C. P. Brown, F. Rosei, E. Traversa, S. Licoccia: Spider Silk as a biomaterial: tailoring mechanical properties via structural modifications. Nanoscale, feature article, 2011, 3, 870-876
♦ M. Stefanelli, S. Nardis, L. Tortora, F. R. Fronczeck, K. M. Smith, S. Licoccia, R. Paolesse: Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand. Chemical Communications, 2011, 47, 4255-4257
♦ D. Pergolesi, E. Fabbri, A. D’Epifanio, E. Di Bartolomeo, A. Tebano, S. Sanna, S. Licoccia, G. Balestrino, E. Traversa: High Proton Conduction in Grain Boundary Free Yttrium-Doped Barium Zirconate Films Grown by Pulsed Laser Deposition. Nature Materials 2010, 9, 846 – 852
♦ S. Sanna, V. Esposito, A. Tebano, S. Licoccia, E. Traversa, G. Balestrino: Enhancement of ionic conductivity in DSC/YSZ heteroepitaxial structures. Small 2010, 6, 1863-1867
♦ E. Fabbri, A. D’Epifanio, S. Sanna, E. Di Bartolomeo, G. Balestrino, S. Licoccia, E. Traversa: A novel single chamber solid oxide fuel cell based on chemically stable thin films of Y-doped BaZrO3 proton conducting electrolyte. Energy and Environmental Science 2010, 3, 618-621
♦ A. Rinaldi, S. Licoccia, E. Traversa, K. Sieradzki, P. Peralta, A. Davila-Ibanez, M. Correa-Duarte, V. Salgueirino: Radial Inner Morphology Effects on the Mechanical Properties of Amorphous Composite Cobalt Boride Nanoparticles. The Journal of Physical Chemistry 2010, 114, 13451-13458
♦ E. Fabbri, D. Pergolesi, S. Licoccia, E. Traversa: Does the Increase in Y-Dopant Concentration Improve the Proton Conductivity of BaZr1-xYxO3-δ Fuel Cell Electrolytes? Solid State Ionics, 2010, 181, 1043-1051
♦ C. Mandoli, F. Pagliari, S. Pagliari, G. Forte, P. Di Nardo, S. Licoccia, E. Traversa: Stem cell aligned growth induced by CeO2 nanoparticles in PLGA scaffolds with improved bioactivity for regenerative medicine. Advanced Functional Materials 2010, 20, 1617-1624
♦ D. Marani, A. D’Epifanio, E. Traversa, M. Miyayama, S. Licoccia: Titania Nanosheets (TNS)/Sulfonated Poly Ether Ether Ketone (SPEEK) Nanocomposite Proton Exchange Membranes for Fuel Cells. Chemistry of Materials, 2010, 22 1126-1133
♦ A. D’Epifanio, M. A. Navarra, F. C. Weise, B. Mecheri, J. Farrington, S. Licoccia, S. Greenbaum: Composite Nafion/sulfonated zirconia membranes: effect of the filler surface properties on proton transport characteristics. Chemistry of Materials 2010, 22, 813-821
♦ C. de Bonis, A. D’Epifanio, M. L. Di Vona, B. Mecheri, E. Traversa, M. Trombetta, S. Licoccia: Proton Conducting Electrolytes based on Silylated and Sulfonated Polyetheretherketone: Synthesis and Characterization. Journal of Polymer Science, Part A, Polymer Chemistry 2010. 33, 2178-2186
♦ A. Rinaldi, P. Peralta, C. Friesen, D. Nahar, S. Licoccia, E. Traversa, K. Sieradzki: Super-hard nanobuttons: constraining crystal plasticity and dealing with extrinsic effects at the nanoscale. Small 2010, 6, 528-536
♦ A. Rainer, M. Centola, C. Spadaccio, G. Gherardi, J. A.Genovese, S. Licoccia, M. Trombetta: Comparative study of different techniques for the sterilization of poly-L-lactide electrospun microfibers: effectiveness vs. material degradation. International Journal of Artificial Organs 2010, 33, 76-85
♦ C. Mandoli, B. Mecheri, G. Forte, F. Pagliari, S. Pagliari, F. Carotenuto, R. Fiaccavento, A. Rinaldi, P. Di Nardo, S. Licoccia, E. Traversa: Thick soft tissue reconstruction on highly perfusive biodegradable scaffolds. Macromolecular Bioscience 2010, 10, 127-138
♦ S. Soliman, S. Pagliari, A. Rinaldi, G. Forte, R. Fiaccavento, F. Pagliari, O. Franzese, M. Minieri, P. Di Nardo, S. Licoccia, E. Traversa: Multiscale three-dimensional scaffolds for tissue engineering via multimodal electron spinning. Acta Biomaterialia 2010, 6, 1227-1237
♦ D. Mirabile Gattia, M. Vittori Antisari, L. Giorgi, R. Marazzi, E. Piscopiello, A. Montone, S. Bellitto, S. Licoccia, E. Traversa: Study of different carbon supports for catalysts: Fuel Cells application. Journal of Power Sources 2009, 194¸243-251
♦ B. Mecheri, A. D’Epifanio, L. Pisani, F. Chen, E. Traversa, F. C. Weise, S. Greenbaum, S. Licoccia: Effect of a proton conducting filler on the physico-chemical properties of SPEEK-based membranes. Fuel Cells 2009, 9, 372-380
♦ C. de Bonis, A. D’Epifanio, M. L. Di Vona, C. D’Ottavi, B. Mecheri, E. Traversa, M. Trombetta, S. Licoccia: Proton conducting hybrid membranes based on aromatic polymers for Direct Methanol Fuel Cell Applications. Fuel Cells 2009, 9, 387-393
♦ E. Fabbri, T. Oh, S. Licoccia, E. Traversa, E. D. Wachsman: Mixed Protonic-Electronic Conductors as Cathode Materials for Proton Conducting Electrolytes in Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs) Journal of The Electrochemical Society 2009, 156, B38-B45
♦ S. Sanna, V. Esposito, D. Pergolesi, A. Orsini, A. Tebano, S. Licoccia, G. Balestrino, E. Traversa: Fabrication and Electrical Properties of Epitaxial Samarium-Doped Ceria Films Onto SrTiO3-Buffered MgO Substrates. Advanced Functional Materials 2009, 19, 1713-1719
♦ E. Fabbri, S. Licoccia, E. Traversa, E. D. Wachsman: Composite Cathodes for Application in Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFCs) Based on Proton Conducting Electrolytes. Fuel Cells 2009, 9, 128-138
♦ M. Zunic, L.Chevallier, F. Deganello, A. D’Epifanio, S. Licoccia, E. Di Bartolomeo, E. Traversa: Electrophoretic deposition of dense Ba Ce0.9Y0.1O3-x electrolyte thick-films on Ni-based anodes for Intermediate Temperature Solid Oxide Fuel Cells (IT_SOFCs). Journal of Power Sources 2009, 190, 417-422
♦ A. Orsini, P.G. Medaglia, S. Sanna, E. Traversa, S. Licoccia, A. Tebano, G. Balestrino: Epitaxial Superlattices of Ionic Conductor Oxides. Superlattices and Microstructures 2009, 46, 223-226
♦ A. Rinaldi, B. Mecheri, V. Garavaglia, S. Licoccia, P. Di Nardo, E. Traversa: Engineering materials and biology to boost performance of microbial fuel cells: a critical review. Energy and Environmental Science 2008, 1, 417-429
Ultra-high dense growth of germanium nanodots on SiO2 thin films
The use of self-organization phenomena at semiconducting surfaces allows fabricating quantum dot structures for producing novel nanodevices with unprecedented applications not only in optoelectronics, but also for room temperature operating single electron transistors and/or resonant tunneling structures. Fabrication of ultra-dense Ge dots on silicon surfaces still presents a series of problems far …
The Icing on the Cake – Combining X-Ray Absorption Spectroscopy with Protein Crystallography (18th September 2007)
Dr. W. Meyer-Klaucke
Nanoengineered silica nanoparticles as intracellular nanoprobes
Nanotechnology is the science of manipulating matter at the atomic and molecular level to obtain materials with specifically enhanced chemical and physical properties. Collaborative research among scientists from Italy – the Nast Centre for Nanoscience Nanotechnology and Innovative Instrumentation, are working in the emerging challanging field of nanomedicine…
Prof. Maurizio De Crescenzi
Contact details
Office: Physics Department
Tel: +39 06 72594547
Lab: +39 06 72594532
Fax: +39+06 2023507
Research Activity
From 1979 his research activity has been focused on the study of the structural and electronic properties of surfaces (clean and interacting with chemisorbed species), and of metal/semiconductor interfaces by means of spectroscopic techniques such as Auger, XPS and Energy Loss in reflection and STM (Scanning Tunneling Microscopy) microscope.
During these years he has contributed actively to the development of some electron spectroscopic techniques as local surface structural tool, as the EELFS (Extended Energy Loss Fine Structure) and the EXFAS (Extended Fine Auger Structure). He has received for this several invited talks and oral presentations at topic Surface Science Conferences.
He has investigated the growth of nanostructures of Germanium/Silicon and Fe/Cu/Si ultrathin films through MBE process. Recently he has synthetized nanotubes of carbon and other materials, such as silicon, and they have been visualized through STM and AFM microscopy.He has been co-author or author of more than 200 international publications concerning electronic and structural properties of the condensed matter and applications of different electron scattering and absorption spectroscopies. He has written a book entitled: ”Electron Scattering and Related Spectroscopies” (World Scientific 1996) providing an overview of all spectroscopic techniques related to electron scattering phenomena. He is in the board of editors of the following international reviews: Journal of Physics (Condensed Matter), Surface Review and Letters, Journal of Electron Spectroscopy.
Recent Publication
[1] P. Castrucci, N. Pinto, L. Morresi, R. Gunnella, R. Murri, M. Scarselli, M. De Crescenzi, “Magnetic properties of thin MnGe films investigated by magnetic force microscopy”, Journal of Magnetism and Magnetic Materials 272-276, 1541 (2004).
[2] F. Ratto, F. Rosei, A. Locatelli, S. Cherifi, S. Fontana, S. Heun, P.-D. Szkutnik, A. Sgarlata, M. De Crescenzi, N. Motta, “Composition of Ge(Si) islands in the growth of Ge on Si(111) by x-ray spectromicroscopy”, Journal of Applied Physics 97, 043516 (2005).
[3] M. De Crescenzi, P. Castrucci, M. Scarselli, M. Diociaiuti, P. S. Chaudari, C. Balasubramanian, T. M. Bhave, S. V. Bhoraskar, “Experimental images of silicon nanotubes”, Applied Physics Letters 86, 231901 (2005). Paper selected to appear on June 1, 2005 of “Virtual Journal of Nanoscale Science & Technology“.
[4] P. Castrucci, M. Scarselli, M. De Crescenzi, M. Diociaiuti, P. Chistolini, M. A. El Khakani, F. Rosei, “Packing-induced electronic structure changes in bundled single-wall carbon nanotubes”, Applied Physics Letters 87, 103106 (2005).
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Cell Sheet Tissue Engineering and Their Clinical Applications (10th September 2007)
Prof. Teruo Okano
Mean Kinetic Energy in Helium mixtures and nanoporous confinement
Collaborative research among scientists from Italy – the Nast Centre for Nanoscience Nanotechnology and Innovative Instrumentation, UK – ISIS Spallation Neutron Source – have studied the single particle microscopic dynamics of helium atoms (3He, 4He) in bulk and confined in silica nanopores, using Deep Inelastic Neutron Scattering (DINS) at the ISIS…
Dr. Roberto Senesi
Contact details
Office: Department of Physics
Tel: +39 06 72594549
Fax: +39 06 2023507
R. Senesi is an experimental physicist with a background in condensed matter and material science. The main Research Topics are: Neutron Scattering, Monoatomic and Molecular Quantum Fluids and solids in bulk and confinement. Experimental determination of the atomic momentum distributions and microscopic structure and dynamics of these systems are carried out using neutron scattering and x-ray and techniques. Relevant examples are: 1) Momentum distribution and kinetic energy in fluid and solid He-3, He-4 and He-3/He-4 mixtures; 2) Kinetic energy of He-4 in nanoporous xerogels; 3) Static structure factor of binary fluid mixtures. R. Senesi has been involved in the design and construction of neutron scattering instruments at the ISIS pulsed neutron facility (UK), such as VESUVIO and e.VERDI, as well as research and development of neutron detection systems for neutrons in the energy range 1- 100 eV. R. Senesi has published more than 60 papers on international journals and presented about 20 scientific contributions at international conferences and schools.
Recent Publications
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R. Senesi, A. Pietropaolo, A. Bocedi, S. E. Pagnotta, F. Bruni, Proton Momentum distribution in a protein hydration shell, Physical Review Letters, 98, 138102 (2007), also in Virtual Journal of Biological Physics Research, 13, issue 7 (2007).
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R. Senesi, D. Colognesi, A. Pietropaolo, T. Abdul-Redah, Deep inelastic neutron scattering from orthorhombic ordered HCl: short-time proton dynamics and anomalous neutron cross-sections, Physical Review B, 72, 054119 (2005).
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C. Andreani, D. Colognesi, J. Mayers, G. Reiter, R. Senesi, Measurement of Momentum Distribution of Light Atoms and Molecules in Condensed Matter Systems Using Inelastic Neutron Scattering, Advances in Physics, 54, 377 (2005).
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C. Andreani, G. Gorini, E. Perelli-Cippo, A. Pietropaolo, N. Rhodes, E. M. Schooneveld, R. Senesi, M. Tarocchi, A resonant detector for high-energy inelastic neutron scattering experiments, Applied Physics Letters, 85, 5454, (2004).
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C. Andreani, C. Pantalei, R. Senesi, Mean kinetic energy of helium atoms in fluid 3He and 3He-4He mixtures, Journal of Physics: Condensed Matter, 18, 5587 (2006).
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R. Senesi, C. Andreani, A. L. Fielding, J. Mayers, W. G. Stirling, Kinetic energy of He atoms in liquid 4He-3He mixtures, Physical Review B, 68, 214522 (2003).
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R. Senesi, C. Andreani, D. Colognesi, A. Cunsolo, M. Nardone, Deep Inelastic Neutron Scattering determination of the single particle kinetic energy in solid and liquid 3He Physical Review Letters, 86, 4584, (2001).
Dr Antonino Pietropaolo
Contact details
Physics Department “G. Occhialini”
University of Milan “Bicocca”
Tel: +39 02 6448 2302
Research activity
AP is an experimental physicist whose research interests concern the dynamics of condensed matter systems and the investigation of the high energy neutron-induced soft errors in electronics, using neutron scattering techniques, and the development of instrumentation for epithermal neutron scattering for applications on materials of cultural heritages interest (epithermal neutron imaging). As far as neutron instrumentation is concerned, AP worked on the development of gamma detectors for the Resonance Detector configuration at the VESUVIO spectrometer at ISIS spallation neutron source and the design and realization of the Very Low Angle Detector (VLAD) bang for High-energy Inelastic Neutron Scattering (HINS) on VESUVIO. In the field of condensed matter, recent experimental studies concerned the short time proton dynamics in bulk and confined water at different thermodynamic states, as well as the sub-femtosecond dynamical properties of the structural hydrogen (silanols) in porous silica xerogels of different porosity. Within the EU-funded ANCIENT CHARM project, AP is developing ancillary equipment and gamma detectors to be used for Neutron Resonance Capture Imaging (NRCI) and neutron tomography on objects of cultural and archaeological interest. A recent experimental activity is related to the test of the new Silicon Photomultiplier (SiPM) coupled to YAP scintillators crystals. Very recently AP, within a joint collaboration of Italian academic institutions and the Science and Technology Facilities Council (STFC), performed the first irradiation experiments on silicon-based Field Programmable Gate Arrays (FPGA) on the VESUVIO beam line, that assessed the suitability of the ISIS source for this kind of investigation.
Recent publications
- R.Senesi, A. Pietropaolo, A. Bocedi, S.E. Pagnotta, F. Bruni, Phys. Rev. Lett. 98, 138102 (2007);
- M. Violante, L. Sterpone, A. Manuzzato, S. Gerardin, P. Rech, M. Bagatin, A. Paccagnella, C. Andreani, G. Gorini , A. Pietropaolo, G. Cardarilli, S. Pontarelli, C. Frost, IEEE Trans. Nucl. Sci. 54, 1184 (2007);
- E. M. Schooneveld, J. Mayers, N. J. Rhodes, A. Pietropaolo, C. Andreani, G. Gorini, E. Perelli-Cippo, R. Senesi, M. Tardocchi, Rev. Sci. Instr. 77, 095103 (2006);
- S. Imberti, C. andreani, V. Garbuio, G. Gorini, A. Pietropaolo, R. Senesi, M. Tarocchi, Nucl. Instr. Meth. A 552, 463 (2005);
- C. Andreani, G. Gorini, E. Perelli-Cippo, A. Pietropaolo, N. Rhodes, E. M. Schooneveld, R.Senesi, M. Tardocchi, Appl. Phys. Lett. 75, 5454 (2004).
Notes: AP is author of about 40 publications on international journals and presented about 20 scientific contributions at international conferences and meetings.